Počet záznamů: 1
The pi Complex of the Hydronium Ion Frozen on the Pathway of Electrophilic Aromatic Substitution
- 1.0463786 - ÚACH 2017 RIV DE eng J - Článek v odborném periodiku
Růžičková, Z. - Holub, Josef - Melichar, Petr - Moncol, J. - Wann, D. A. - Fanfrlík, Jindřich - Růžička, A. - Hnyk, Drahomír
The pi Complex of the Hydronium Ion Frozen on the Pathway of Electrophilic Aromatic Substitution.
European Journal of Organic Chemistry. Roč. 2016, č. 26 (2016), s. 4473-4475. ISSN 1434-193X. E-ISSN 1099-0690
Grant CEP: GA ČR(CZ) GBP208/12/G016
Institucionální podpora: RVO:61388980 ; RVO:61388963
Klíčová slova: Anions * Pi complexes * Electrophilic substitution * Quantum mechanics * Structure elucidation
Kód oboru RIV: CA - Anorganická chemie; CF - Fyzikální chemie a teoretická chemie (UOCHB-X)
Impakt faktor: 2.834, rok: 2016
A very rare crystal was prepared consisting of a 2D aromatic (toluene) together with a weakly coordinating 3D aromatic (closo-1-CB11H12-) and a hydronium ion, and this crystal was analyzed by using X-ray diffraction and high-level quantum-mechanical calculations. The nature of the crystal arrangement made it possible to detect the frozen complex that would originate during protonation of toluene by the acidic hydronium ion.
Trvalý link: http://hdl.handle.net/11104/0262872
Počet záznamů: 1