Enantioselective hydrogenation of cyclic imines catalysed by Noyori-Ikariya half-sandwich complexes and their analogues

0459401 - ÚOCHB 2017 RIV GB eng J - Článek v odborném periodiku
Vilhanová, B. - Václavík, Jiří - Šot, P. - Pecháček, J. - Zápal, J. - Pažout, R. - Maixner, J. - Kuzma, M. - Kačer, P.
Enantioselective hydrogenation of cyclic imines catalysed by Noyori-Ikariya half-sandwich complexes and their analogues.
Chemical Communications. Roč. 52, č. 2 (2016), s. 362-365. ISSN 1359-7345. E-ISSN 1364-548X
Institucionální podpora: RVO:61388963
Klíčová slova: asymmetric transfer hydrogenation * ruthenium catalysts * aromatic ketones
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 6.319, rok: 2016
http://pubs.rsc.org/en/content/articlepdf/2016/cc/c5cc06712j

A method for enantioselective hydrogenation of cyclic imines with gaseous hydrogen has been developed. Easily accessible Noyori-Ikariya Ru(II) and Rh(III) complexes can be used directly without an inert atmosphere. Substrate activation has been achieved by trifluoroacetic acid. A new hydroxyl-functionalized complex is reported, showing high activity in transfer hydrogenation.
Trvalý link: http://hdl.handle.net/11104/0259602