Titanocene sulfide chemistry

0458271 - ÚFCH JH 2017 RIV NL eng J - Článek v odborném periodiku
Horáček, Michal
Titanocene sulfide chemistry.
Coordination Chemistry Reviews. Roč. 314, MAY 2016 (2016), s. 83-102. ISSN 0010-8545. E-ISSN 1873-3840
Grant CEP: GA ČR(CZ) GAP207/12/2368
Institucionální podpora: RVO:61388955
Klíčová slova: titanocene sulfide chemistry * photolysis * titanocene hydrosulfides Ti-(SH)n
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 13.324, rok: 2016

This review is focused on the chemistry of titanocene sulfide compounds. The linking element for all compounds discussed in this review is the presence of a bent titanocene fragment consisting of two aromatic cyclopentadienyl rings and one electron deficient central titanium atom coordinated between them. Several types of sulfur ligands bonding to titanocene fragment, such as hydrosulfide, sulfide or thiolate are described, as well as the various types of sulfur ligand functions in titanocene complexes have been observed. The titanocene sulfide chemistry is more than fifty years old, but since it is still evolving, it offers a plethora of surprises and challenges.
Trvalý link: http://hdl.handle.net/11104/0258555