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Unexpected Formation of Disulfide-based Biscalix[4]arenes
- 1.0454479 - ÚCHP 2016 RIV GB eng J - Článek v odborném periodiku
Stejskal, F. - Cuřínová, Petra - Lhoták, P.
Unexpected Formation of Disulfide-based Biscalix[4]arenes.
Tetrahedron. Roč. 72, č. 5 (2016), s. 760-766. ISSN 0040-4020. E-ISSN 1464-5416
Institucionální podpora: RVO:67985858
Klíčová slova: calixarene * bridging reaction * complexation
Obor OECD: Organic chemistry
Impakt faktor: 2.651, rok: 2016
Attempts at Pd-catalyzed bridging in sulfoxide-bearing calixarenes containing various substituents/n(phenyl, ethyl, pyrimidin-2-yl) gave the expected compound only in the case of the ethyl derivative./nHowever, the reaction of sulfoxides with BuLi revealed the ability of the pyrimidin-2-yl group to function unexpectedly as a leaving group. This enabled, depending on the reaction conditions, preparation of unique bis-calixarenes connected together via two sulfur atoms spacers: eSeSe, eS(O)eSe or eS(O)2eSe. As documented by 1H NMR titrations these compounds, otherwise not easily accessible by common synthetic methods, showed recognition ability towards selected cations of the N-methylpyridinium type.
Trvalý link: http://hdl.handle.net/11104/0255274
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