Fullerene recognition by 5-nitro-11,17,23,29-tetramethylcalix[5]arene

0452179 - ÚFCH JH 2016 RIV GB eng J - Článek v odborném periodiku
Flídrová, K. - Liška, Alan - Ludvík, Jiří - Eigner, V. - Lhoták, P.
Fullerene recognition by 5-nitro-11,17,23,29-tetramethylcalix[5]arene.
Tetrahedron Letters. Roč. 56, č. 12 (2015), s. 1535-1538. ISSN 0040-4039. E-ISSN 1873-3581
Grant CEP: GA ČR GA13-21704S
Institucionální podpora: RVO:61388955
Klíčová slova: calixarene * fullerene * complexation
Kód oboru RIV: CG - Elektrochemie
Impakt faktor: 2.347, rok: 2015

The condensation of different building blocks allows the synthesis of an electrochemically active 5-nitro-11,17,23,29-tetramethylcalix[5]arene that was designed to study fullerene complexation using cyclic voltammetry. Although this method was ultimately unsuccessful, the formation of complexes between the calix[5]arene derivative and C-60 or C-70 fullerenes in solution was proved by mass spectrometry. Moreover, the solid state structure of the complex with fullerene C-60 was confirmed by X-ray crystallography. (C) 2015 Elsevier Ltd. All rights reserved.
Trvalý link: http://hdl.handle.net/11104/0253200