Ten-vertex dicarbaboranes from nido-5,6-C2B8H12

0445940 - ÚACH 2016 RIV CH eng J - Článek v odborném periodiku
Štíbr, Bohumil
Ten-vertex dicarbaboranes from nido-5,6-C2B8H12.
Journal of Organometallic Chemistry. Roč. 798, DEC (2015), s. 30-35. ISSN 0022-328X. E-ISSN 1872-8561
Grant CEP: GA ČR(CZ) GAP207/11/0705
Institucionální podpora: RVO:61388980
Klíčová slova: Boron * Carboranes * Dicarbaboranes * Mechanisms
Kód oboru RIV: CA - Anorganická chemie
Impakt faktor: 2.336, rok: 2015

The chemistry of the nido-5,6-C2B8H12 dicarbaborane, the most significant compound of the 10-vertex dicarbaborane series, has been discussed in this review within the contexts of reactivity and reaction mechanism. Chemical transformations of this carborane led to the isolation of the whole series of other compounds that now start playing ever increasing role in developing new carborane chemistry. Overviewed are procedures leading to closo and open-structured (nido and arachno) dicarbaboranes together with principles of their substitution on cluster-carbon and boron vertexes.
Trvalý link: http://hdl.handle.net/11104/0247958