Novel NMR Method for Organic Aerosol Analysis

0445026 - ÚCHP 2016 CZ eng K - Konferenční příspěvek (tuzemská konf.)
Horník, Štěpán
Novel NMR Method for Organic Aerosol Analysis.
Proceedings of abstracts. Prague: Institute of Chemical Process Fundamental of the CAS, v. v. i, 2015 - (Bendová, M.; Wagner, Z.), s. 20-21. ISBN 978-80-86186-70-2.
[Bažant Postgraduate Conference 2015. Prague (CZ)]
Institucionální podpora: RVO:67985858
Klíčová slova: nmr method * organic aerosol composition * analysis
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie

The suitability of ChenomX was performed both on real atmospheric aerosols and model samples of coal combustion. Up to 30 compounds were found in analyzed samples. Most abundant substances were mono- and dicarboxylic acids (formic, acetic, succinic acid) and their derivatives (lactic acid), followed by carbohydrates, anhydro saccharides and sugar alcohols (levoglucosan, fructose, D-threitol), and amines (methylamine, dimethylamine). The real aerosol sample was also analyzed on four different NMR spectrometers (500, 600, 700, 800 MHz) in order to enhance the resolution and find less abundant substances. The frequencies of the spectrometers were chosen according to the ChenomX database. In the 800 MHz spectrum ca. 50 compounds were identified.
Trvalý link: http://hdl.handle.net/11104/0247441