Počet záznamů: 1
Synthesis of tetrafluoroethyl- and tetrafluoroethylene-containing amines by the reaction of silanes with enamines under acidic conditions
- 1.0443913 - ÚOCHB 2016 RIV CH eng J - Článek v odborném periodiku
Chernykh, Yana - Jurásek, Bronislav - Beier, Petr
Synthesis of tetrafluoroethyl- and tetrafluoroethylene-containing amines by the reaction of silanes with enamines under acidic conditions.
Journal of Fluorine Chemistry. Roč. 171, SI (2015), s. 162-168. ISSN 0022-1139. E-ISSN 1873-3328
Grant CEP: GA ČR GAP207/11/0421
Institucionální podpora: RVO:61388963
Klíčová slova: nucleophilic addition * enamines * iminium salts * tetrafluoroethyl * tetrafluoroethylene
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 2.213, rok: 2015
Enamines with in situ formed hydrogen fluoride underwent efficient reaction with trimethyl(1,1,2,2tetrafluoro-2-(phenylthio)ethyl)silane and trimethyl(1,1,2,2-tetrafluoro-2-(phenylsulfonyl)ethyl)silane. Radical or reductive desulfurization of the addition products provided amines containing the tetrafluoroethyl group.
Trvalý link: http://hdl.handle.net/11104/0246570
Počet záznamů: 1