Transformations of functional groups attached to cyclopentadienyl or related ligands in group 4 metal complexes

0443393 - ÚFCH JH 2016 RIV NL eng J - Článek v odborném periodiku
Pinkas, Jiří - Lamač, Martin
Transformations of functional groups attached to cyclopentadienyl or related ligands in group 4 metal complexes.
Coordination Chemistry Reviews. Roč. 296, JUL 2015 (2015), s. 45-90. ISSN 0010-8545. E-ISSN 1873-3840
Grant CEP: GA ČR(CZ) GA14-08531S
Institucionální podpora: RVO:61388955
Klíčová slova: Zirconium * Functionalized cyclopentadienyl ligands * Titanium
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 12.994, rok: 2015

Functional groups attached to η5-coordinated cyclopentadienyl or related (indenyl, fluorenyl) ligands in transition metal complexes may be subjected to various synthetic transformations giving rise to novel, often otherwise inaccessible organometallic derivatives. Alternatively, this approach may eliminate the necessity of previous elaborate ligand synthesis. A number of synthetic methods have appeared in the recent past, which are compatible even with reactive electrophilic early transition metal compounds. This review article summarizes the development of functional group chemistry performed at group 4 metallocene, half-sandwich, and related complexes.
Trvalý link: http://hdl.handle.net/11104/0246124