Low-dimensional compounds containing cyanido groups. XXVI. Crystal structure, spectroscopic and magnetic properties of Co(II) complexes with non-linear pseudohalide ligands

0434737 - FZÚ 2015 RIV GB eng J - Článek v odborném periodiku
Váhovská, L. - Potočňák, I. - Vitushkina, S. - Dušek, Michal - Titiš, J. - Boča, R.
Low-dimensional compounds containing cyanido groups. XXVI. Crystal structure, spectroscopic and magnetic properties of Co(II) complexes with non-linear pseudohalide ligands.
Polyhedron. Roč. 81, Oct (2014), s. 396-408. ISSN 0277-5387. E-ISSN 1873-3719
Institucionální podpora: RVO:68378271
Klíčová slova: cobalt * dicyanamide * tricyanomethanide * crystal structure * magnetism
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 2.011, rok: 2014

From the systems Co(II) - L - C(CN)3(-)/N(CN)2(-) (L = 2,20-bipyridine (bpy) or 1,10-phenanthroline (phen)), two dicyanamide (dca, N(CN2(-)) and three tricyanomethanide (tcm, C(CN)3(-)) complexes, [Co(phen)2(dca)2] (1a, 1b) [Co(phen)2](tcm)2 (2), [{Co(phen)2(μ1-tcm)}2(μ1,5,5-tcm)]tcm.H2O (3), [Co(bpy)(μ1,5-tcm)2]n (4) and [Co(bpy)(μ1,5-dca)2]n (5), were isolated and characterized by X-ray crystallography, spectral and magnetic measurements. Their magnetic properties were studied, too.
Trvalý link: http://hdl.handle.net/11104/0238733