Control over the self-assembly and dynamics of metallacarborane nanorotors by the nature of the polymer matrix: a solid-state NMR study

0432034 - ÚMCH 2015 RIV US eng J - Článek v odborném periodiku
Brus, Jiří - Zhigunov, Alexander - Czernek, Jiří - Kobera, Libor - Uchman, M. - Matějíček, P.
Control over the self-assembly and dynamics of metallacarborane nanorotors by the nature of the polymer matrix: a solid-state NMR study.
Macromolecules. Roč. 47, č. 18 (2014), s. 6343-6354. ISSN 0024-9297. E-ISSN 1520-5835
Grant CEP: GA ČR(CZ) GA14-03636S; GA ČR(CZ) GA14-14608S; GA MŠMT(CZ) LD14010
Grant ostatní: European Commission(XE) MPNS COST Action MP1202
Institucionální podpora: RVO:61389013
Klíčová slova: self-assembly * metallacarboranes * polymers
Kód oboru RIV: CD - Makromolekulární chemie
Impakt faktor: 5.800, rok: 2014

Solids that combine long-range order with rapid molecular reorientation offer a promising approach for the development of a novel class of functional materials with potential applications in materials science and nanotechnology. In this contribution, the capability of dicarbollide ions to undergo self-assembly processes with suitable macromolecules is demonstrated, and a strategy leading to the formation of structurally and dynamically well-defined amphidynamic polymeric composites is introduced.
Trvalý link: http://hdl.handle.net/11104/0237267