Tailoring the magnetic properties and magnetorheological behavior of spinel nanocrystalline cobalt ferrite by varying annealing temperature

0427302 - ÚH 2015 RIV GB eng J - Článek v odborném periodiku
Sedlacik, M. - Pavlinek, V. - Peer, Petra - Filip, Petr
Tailoring the magnetic properties and magnetorheological behavior of spinel nanocrystalline cobalt ferrite by varying annealing temperature.
Dalton Transactions. Roč. 18, č. 43 (2014), s. 6919-6924. ISSN 1477-9226. E-ISSN 1477-9234
Grant CEP: GA ČR GA202/09/1626
Grant ostatní: GA MŠk(CZ) ED2.1.00/03.0111
Institucionální podpora: RVO:67985874
Klíčová slova: spinel nanocrystalline cobalt ferrite * nanoparticles * magnetorheological effect
Obor OECD: Fluids and plasma physics (including surface physics)
Impakt faktor: 4.197, rok: 2014

Magnetic nanoparticles of spinel nanocrystalline cobalt ferrite were synthesized via the sol–gel method and subsequent annealing. The influence of the annealing temperature on the structure, magnetic properties, and magnetorheological effect was investigated. The finite crystallite size of the particles, determined by X-ray diffraction and the particle size observed via transmission electron microscopy, increased with the annealing temperature. The magnetic properties observed via a vibrating sample magnetometer showed that an increase in the annealing temperature leads to the increase in the magnetization saturation and, in contrast, a decrease in the coercivity. The effect of annealing on the magnetic properties of ferrite particles has been explained by the recrystallization process at high temperatures. This resulted in grain size growth and a decrease in an imposed stress relating to defects in the crystal lattice structure of the nanoparticles. The magnetorheological characteristics of suspensions of ferrite particles in silicone oil were measured using a rotational rheometer equipped with a magnetic field generator in both steady shear and small-strain oscillatory regimes. The magnetorheological performance expressed as a relative increase in the magnetoviscosity appeared to be significantly higher for suspensions of particles annealed at 1000 °C.
Trvalý link: http://hdl.handle.net/11104/0233059