Počet záznamů: 1
Molecular Structure Effects in the Asymmetric Transfer Hydrogenation of Functionalized Dihydroisoquinolines on (S,S)-[RuCl(eta (6)-p-cymene)TsDPEN]
- 1.0425867 - MBÚ 2014 RIV US eng J - Článek v odborném periodiku
Václavík, J. - Pecháček, J. - Vilhanová, B. - Šot, P. - Januščák, J. - Matoušek, V. - Přech, J. - Bártová, Simona - Kuzma, Marek - Kačer, P.
Molecular Structure Effects in the Asymmetric Transfer Hydrogenation of Functionalized Dihydroisoquinolines on (S,S)-[RuCl(eta (6)-p-cymene)TsDPEN].
Catalysis Letters. Roč. 143, č. 6 (2013), s. 555-562. ISSN 1011-372X. E-ISSN 1572-879X
Grant CEP: GA ČR GA104/09/1497; GA ČR GAP106/12/1276
Grant ostatní: GA MŠk(CZ) LM2010005
Institucionální podpora: RVO:61388971
Klíčová slova: ATH * Kinetics * Imines
Kód oboru RIV: CB - Analytická chemie, separace
Impakt faktor: 2.291, rok: 2013
The asymmetric transfer hydrogenation of five dihydroisoquinolines (DHIQs) was studied by NMR spectroscopy. The DHIQs differed by substitution with methoxy groups, which had a significant effect upon the reaction performance in terms of reaction rate and enantioselectivity. The differences are most probably related to the basicity of DHIQs.
Trvalý link: http://hdl.handle.net/11104/0231660
Počet záznamů: 1