Atmospheric-pressure microwave torch discharge generated γ-Fe2O3 nanopowder

0421345 - ÚFM 2014 RIV NL eng J - Článek v odborném periodiku
David, Bohumil - Schneeweiss, Oldřich - Pizúrová, Naděžda - Šantavá, Eva - Kudrle, V. - Synek, P. - Jašek, O.
Atmospheric-pressure microwave torch discharge generated γ-Fe2O3 nanopowder.
Physics Procedia. Roč. 44, č. 1 (2013), s. 206-212. ISSN 1875-3892.
[International Conference on Solid State Chemistry /10./. Pardubice, 10.06.2012-14.06.2012]
Grant CEP: GA ČR GA106/08/1440; GA ČR GA202/08/0178; GA MŠMT(CZ) ED1.1.00/02.0068; GA MŠMT 1M0512
Výzkumný záměr: CEZ:AV0Z10100520
Institucionální podpora: RVO:68081723
Klíčová slova: maghemite * microwave discharge * Mossbauer spectroscopy * magnetic measurements
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus

Microwave torch discharge ignited in Ar at 1 bar was used for the synthesis of γ-Fe2O3 nanoparticles. A double-walled nozzle electrode enabled to introduce gases separately: Ar flowed in the central channel, whereas the mixture of H2/O2/Fe(CO)5 was added into the torch discharge through an outer channel. The composition and properties of the synthesized nanopowders were studied by TEM, XRD, Raman and Mössbauer spectroscopies. Basic magnetic measurements at low/high temperatures were performed. The γ-Fe2O3 phase with the mean crystallite size of 24 nm was identified by XRD in the representative sample. The measured Raman spectrum matched well those reported for γ-Fe2O3 powders in the literature. In the transmission Mössbauer spectrum measured at 5 K the two sextets characteristic for γ Fe2O3 were clearly identified. No change in specific magnetic moment typical of Fe3O4 at its Verwey temperature was observed on the zero field curve, which smoothly increased with temperature. Neither Fe3O4 nor Fe2O3 were present in the sample. We also report on the high temperature magnetic properties of the representative sample and describe its structural changes and phase transformations up to 1073 K.
Trvalý link: http://hdl.handle.net/11104/0228239