Centrifugal spray singlet oxygen generator for a COIL with nitrogen as a buffer gas

0399062 - FZÚ 2014 RIV US eng C - Konferenční příspěvek (zahraniční konf.)
Špalek, Otomar - Jirásek, Vít - Čenský, Miroslav - Kodymová, Jarmila
Centrifugal spray singlet oxygen generator for a COIL with nitrogen as a buffer gas.
XIX International Symposium on High-Power Laser Systems and Applications 2012. Bellingham: SPIE, 2013 - (Allakhverdiev, K.), s. 867706. Proceedings of SPIE, 8677. ISBN 978-0-8194-9455-9. ISSN 0277-786X.
[International Symposium on High-Power Laser Systems and Applications (HPLS&A) /19./. Istanbul (TR), 10.09.2012-14.09.2012]
Grant ostatní: LASTEC(IN) LASTEC/RKT/53/10-11; US Air Force EOARD(US) FA8655-09-1-3091
Institucionální podpora: RVO:68378271
Klíčová slova: Chemical Oxygen-Iodine Laser * COIL * spray generator * singlet oxygen * centrifugal separation
Kód oboru RIV: BH - Optika, masery a lasery

Operation parameters of originally designed Centrifugal Spray Singlet Oxygen Generator (CSSOG) for pumping a Chemical Oxygen-Iodine Laser (COIL) were studied using nitrogen as a buffer gas instead of helium used previously. In CSSOG, singlet oxygen is generated by the reaction between gaseous chlorine and basic hydrogen peroxide (BHP) in a form of a very fine spray. This system with a high interfacial surface area enables a very high reaction rate. A depleted BHP liquid in the reaction with chlorine is fast separated from gas containing singlet oxygen by means of a specially designed centrifugal gas-liquid separator. The experiments with the modified CSSOG for operation with much cheaper nitrogen instead of helium proved the effective production of singlet oxygen with a yield of 0.4 - 0.8 at even very high generator pressures (260 - 450 Torr).
Trvalý link: http://hdl.handle.net/11104/0226451