N2O Catalytic Decomposition – from Laboratory Experiment to Industry Reactor

0398556 - ÚCHP 2014 RIV NL eng J - Článek v odborném periodiku
Obalová, L. - Jirátová, Květa - Karásková, K. - Chromčáková, Ž.
N2O Catalytic Decomposition – from Laboratory Experiment to Industry Reactor.
Catalysis Today. Roč. 191, č. 1 (2012), s. 116-120. ISSN 0920-5861. E-ISSN 1873-4308
Grant CEP: GA TA ČR TA01020336
Institucionální podpora: RVO:67985858
Klíčová slova: N2O * catalytic decomposition * fixed bed reactor
Kód oboru RIV: CI - Průmyslová chemie a chemické inženýrství
Impakt faktor: 2.980, rok: 2012

Paper deals with design of pilot reactor for low temperature N2O decomposition in off-gases from HNO3 production. Pseudo-homogeneous one-dimensional model of an ideal plug flow reactor was used for modeling of N2O decomposition in a laboratory fixed bed reactor filled with grains or pellets of a Co–Mn–Al mixed oxide catalyst. Increase in inlet pressure up to 0.6 MPa did not influence the effective diffusion coefficient, but improved the achieved N2O conversion. Based on the laboratory data of N2O decomposition over Co–Mn–Al mixed oxide pellets, catalyst bed of 3400 kg was estimated for target 90% N2O conversion (30 000 m3 h−1 of exhaust gases from HNO3 plant containing 0.1 molar% N2O, 0.01 molar% NO, 0.01 molar% NO2, 3 molar% H2O, 5 molar% O2) at 420 °C and 600 kPa inlet pressure.
Trvalý link: http://hdl.handle.net/11104/0226027