0397463 - FZÚ 2014 RIV AT eng J - Článek v odborném periodiku
Tabatabaee, M. - Mahmoodikhah, H. - Ahadiat, G. - Dušek, Michal - Pojarová, Michaela
Synthesis, crystal structure, and spectroscopic characterization of two new binuclear complexes of manganese(II) and vanadium(V) with dipicolinate ligands containing 2-aminopyrimidinium as a counter cation.
Monatshefte fur Chemie. Roč. 144, č. 5 (2013), s. 621-626. ISSN 0026-9247. E-ISSN 1434-4475
Grant CEP: GA ČR(CZ) GAP204/11/0809
Institucionální podpora: RVO:68378271
Klíčová slova: manganese complex * vanadium complex * dipicolinic ligand * crystal structure
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 1.347, rok: 2013

Two new binuclear complexes were synthesized by a hydrothermal process and characterized by elemental analysis, IR spectroscopy, thermal analysis, and X-ray single crystal diffraction. Both compounds contain two Hamp cations and a dinuclear manganese(II) or vanadium(V) anion complex. Two manganese(II) ions are bridged by pyridine-2,6-dicarboxylate ions in the manganese complex,and they are both coordinated in a distorted pentagonal-bipyramidal geometry. Vanadium(V) ions are coordinated octahedrally. The crystal structures of both complexes are stabilized by a complex network of hydrogen bonds.
Trvalý link: http://hdl.handle.net/11104/0225085