Liquid-Liquid Equilibria in Systems of 1-[(1R,2S,5R)-(‒)-Menthoxymethyl]-3-alkylimidazolium NTf2 Chiral Ionic Liquids with 1-Octanol

0394019 - ÚCHP 2014 NL eng C - Konferenční příspěvek (zahraniční konf.)
Aim, Karel - Andresová, Adéla - Feder-Kubis, J. - Wagner, Zdeněk - Jacquemin, J. - Bendová, Magdalena
Liquid-Liquid Equilibria in Systems of 1-[(1R,2S,5R)-(‒)-Menthoxymethyl]-3-alkylimidazolium NTf2 Chiral Ionic Liquids with 1-Octanol.
Scientific Programme. -: -, 2013, s. 1362. ISBN N.
[European Congress of Chemical Engineering /9./. The Hague (NL), 21.04.2013-25.04.2013]
Institucionální podpora: RVO:67985858
Klíčová slova: chiral ionic liquids * liquid-liquid equilibria * COSMO-RS
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
http://www.ecce2013.eu/index.php

In this contribution, selected members of the homologous series of 1-[(1R,2S,5R)-(‒)-menthoxymethyl]-3-alkylimidazolium NTf2 chiral ionic liquids with alkyl ranging from methyl to dodecyl were studied. Liquid-liquid equilibria of the studied CILs with 1-octanol was determined using the cloud-point method and the direct analytical (shake-flask) method. The experimental data were then correlated by the modified Flory-Huggins equation and compared with a COSMO-RS prediction.
Trvalý link: http://hdl.handle.net/11104/0222350