Počet záznamů: 1
Synthesis, Molecular Structure, and Electrochemistry of 1-Ferrocenyl-1,2-dicarba-closo-dodecaboranes
- 1.0393413 - ÚOCHB 2014 RIV DE eng J - Článek v odborném periodiku
Korotvička, A. - Šnajdr, I. - Štěpnička, P. - Císařová, I. - Janoušek, Zbyněk - Kotora, M.
Synthesis, Molecular Structure, and Electrochemistry of 1-Ferrocenyl-1,2-dicarba-closo-dodecaboranes.
European Journal of Inorganic Chemistry. -, č. 15 (2013), s. 2789-2798. ISSN 1434-1948. E-ISSN 1099-0682
Grant ostatní: GA ČR(CZ) GAP207/11/0338; GAČR(CZ) GAP207/11/0705
Program: GA
Institucionální podpora: RVO:61388963
Klíčová slova: carboranes * metallocenes * structure elucidation * electrochemistry * addition
Kód oboru RIV: CA - Anorganická chemie
Impakt faktor: 2.965, rok: 2013
Bis(dimethylsulfido)decaborane, 6,9-(Me2S)2-arachno-B10H12, reacts smoothly with ferrocenyl alkynes FcCCR [1ah; Fc = ferrocenyl, R = H (1a), CH3 (1b), Ph (1c), 4-MeO2CC6H4 (1d), Fc (1e), CCFc (1f), C(O)CH3 (1g), and CO2CH2CH3 (1h)] to afford the corresponding 1-ferrocenyl-1,2-dicarba-closo-dodecaboranes 2ah in good yields. Ester 2h was further reduced to the respective hydroxymethyl derivative, 1-Fc-2-CH2OH-1,2-closo-C2B10H10 (3). The reaction of 6,9-(Me2S)2-B10H12 with FcCCSiMe3 proceeded in a different manner to produce (among other products) an SMe2 adduct of an opened decaborane substituted with a 2-ferrocenyl-2-(trimethylsilyl)ethen-1-yl group (4). This compound probably results through hydroboration of the starting alkyne and migration of the SiMe3 group. All prepared compounds were characterized by spectroscopic methods (1H, 13C, and 11B NMR spectroscopy, IR spectroscopy, and mass spectrometry), and their molecular structures were determined by single-crystal X-ray diffraction analysis. In addition, the compounds were studied by cyclic and differential pulse voltammetry on a platinum disc electrode to reveal simple ferrocenyl-centered oxidations for the singly ferrocenylated carboranes and two consecutive oxidation waves for compounds 2e and 2f, which possess two ferrocenyl substituents.
Trvalý link: http://hdl.handle.net/11104/0222193
Počet záznamů: 1