High dynamic range isotope ratio measurements using an analog electron multiplier

0387686 - ÚFE 2014 RIV GB eng J - Článek v odborném periodiku
Williams, P. - Lorinčík, Jan - Franzreb, K. - Herwig, R.
High dynamic range isotope ratio measurements using an analog electron multiplier.
Surface and Interface Analysis. Roč. 45, č. 1 (2013), s. 549-552. ISSN 0142-2421. E-ISSN 1096-9918
Grant CEP: GA MŠMT ME 894
Institucionální podpora: RVO:67985882
Klíčová slova: Isotope ratios * electron multiplier * dynamic range
Kód oboru RIV: JA - Elektronika a optoelektronika, elektrotechnika
Impakt faktor: 1.393, rok: 2013

We have explored measurement and accuracy issues in the use of an electron multiplier (EM) detector as a fast analog amplifier rather than in pulse-counting mode. EM on a Cameca IMS 3f instrument was modified to allow both analog and digital signals to be recorded simultaneously. The digital signal was picked up on the last dynode and the analog signal was recorded at the anode (operated near ground potential). The digital signal was differentiated to convert the positive pulse at the last dynode to a negative-going signal that could be processed by the digital electronics of the IMS 3f and fed into the pulse counting system. The analog signal was amplified by an operational amplifier with a 106 ohm feedback resistor and the resulting signal was fed into the voltage/frequency convertor that normally processes the electrometer output from the Faraday cup collector. Isotope ratio measurements were explored for negative ion signals of the silicon and sulfur isotopes under Cs+ primary ion bombardment. For 32S and 34S signals of ~ 3 _ 107 and ~ 1.3 _ 106 counts/s respectively and 1 s counting times for each isotope, the standard deviations of the means of 140 ratio measurements averaged 0.3 per mil. Measurements on two sulfide samples with isotope ratios previously determined to differ by 13.6 per mil were within 1.2_0.5 per mil of the previous difference value. Sources of residual error are discussed
Trvalý link: http://hdl.handle.net/11104/0222059