Experiments and Modelling of Liquid–liquid Equilibria in the Mineral Oil + N,N-dimethylformamide System

0383062 - ÚCHP 2013 RIV NL eng J - Článek v odborném periodiku
Sedláková, Zuzana - Andresová, Adéla - Morávková, Lenka - Bogdanić, Grozdana
Experiments and Modelling of Liquid–liquid Equilibria in the Mineral Oil + N,N-dimethylformamide System.
Procedia Engineering. Roč. 42, SI (2012), s. 721-725. E-ISSN 1877-7058.
[International Congress of Chemical and Process Engineering CHISA 2012 and 15th Conference PRES 2012 /20./. Prague, 25.08.2012-29.08.2012]
Institucionální podpora: RVO:67985858
Klíčová slova: mineral iol * liquid-liquid equilibria * binodal curve
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie

Description of phase behaviour of a highly nonideal system mineral oil + DMF is a rather complex task, because hydrocarbon feed, which has to be separated into aromatic and nonaromatic fractions, consists of large number of compounds that differ significantly in molecular weight and chemical structure. Such a complex mixture was substituted by two pseudo-components, aromatic and nonaromatic in order to simplify the procedure. They were represented by adequate model compounds, whose thermodynamic behaviour was similar to the original one. The chosen model system simulates properly the real one in the sense of the mutual solubility of aromatic and nonaromatic components. However, this simplification of description of strongly nonideal mixtures should be considered as the first approximation.
Trvalý link: http://hdl.handle.net/11104/0216320