Počet záznamů: 1
Proton affinities of 2-iminoimidazolines with bulky N-alkyl-substituents
- 1.0379165 - ÚOCHB 2013 RIV NL eng J - Článek v odborném periodiku
Polyakova, Svetlana - Kunetskiy, Roman Alexejevič - Schröder, Detlef
Proton affinities of 2-iminoimidazolines with bulky N-alkyl-substituents.
International Journal of Mass Spectrometry. Roč. 314, 15 Mar (2012), s. 13-17. ISSN 1387-3806. E-ISSN 1873-2798
Grant ostatní: European Research Council(XE) AdG HORIZOMS
Výzkumný záměr: CEZ:AV0Z40550506
Klíčová slova: collision-induced dissociation * electrospray ionization * iminoimidazolines * kinetic method * proton affinity
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 2.142, rok: 2012
The gas-phase proton affinities of 2-iminoimidazolines with bulky substituents on the ring-nitrogen atoms are investigated by the kinetic method. The experimental results are complemented by calculations using density functional theory. It turns out that the title compounds can be termed as superbases with the largest proton affinities ranging up to 260 kcal mol(-1).
Trvalý link: http://hdl.handle.net/11104/0210427
Počet záznamů: 1