A Highly Luminescent Hexanuclear Molybdenum Cluster - A Promising Candidate toward Photoactive Materials

0378635 - ÚACH 2013 RIV DE eng J - Článek v odborném periodiku
Kirakci, Kaplan - Kubát, Pavel - Dušek, Michal - Fejfarová, Karla - Šícha, Václav - Mosinger, Jiří - Lang, Kamil
A Highly Luminescent Hexanuclear Molybdenum Cluster - A Promising Candidate toward Photoactive Materials.
European Journal of Inorganic Chemistry. Roč. 2012, č. 19 (2012), s. 3107-3111. ISSN 1434-1948. E-ISSN 1099-0682
Grant CEP: GA ČR(CZ) GAP204/11/0809; GA ČR GAP208/10/1678
Institucionální podpora: RVO:61388980 ; RVO:61388955 ; RVO:68378271
Klíčová slova: cluster compounds * luminescence * molybdenum * organic-inorganic hybrid composites * singlet oxygen
Kód oboru RIV: CA - Anorganická chemie
Impakt faktor: 3.120, rok: 2012

A new Mo-6 cluster complex and its silica and polyurethane composites have been synthesized and characterized. These materials are highly luminescent with emission above 650 nm, produce singlet oxygen with high efficiency, are photostable, and can be excited up to 580 nm. These properties are desirable for the construction of luminescent probes of oxygen, photoactive materials for oxidation reactions with easily separable active carriers, and bactericidal textile surfaces upon daylight irradiation.
Trvalý link: http://hdl.handle.net/11104/0210056