Počet záznamů: 1
Experimental and theoretical study on complexation of the ammonium cation with dibenzo-30-crown-10
- 1.0376365 - ÚMCH 2013 RIV AT eng J - Článek v odborném periodiku
Makrlík, E. - Toman, Petr - Vaňura, P.
Experimental and theoretical study on complexation of the ammonium cation with dibenzo-30-crown-10.
Monatshefte fur Chemie. Roč. 143, č. 5 (2012), s. 711-715. ISSN 0026-9247. E-ISSN 1434-4475
Grant CEP: GA ČR(CZ) GAP205/10/2280
Výzkumný záměr: CEZ:AV0Z40500505
Klíčová slova: crown ethers * macrocycles * complexation
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 1.629, rok: 2012
From extraction experiments in the two-phase water–nitrobenzene system and γ-activity measurements, the stability constant of the dibenzo-30-crown-10•NH4+ complex species dissolved in nitrobenzene saturated with water was determined. By use of quantum-mechanical calculations, the most probable structures of this complex species were predicted.
Trvalý link: http://hdl.handle.net/11104/0006954
Počet záznamů: 1