Silica and Silicates in Modern Catalysis

0376137 - ÚFCH JH 2012 RIV IN eng M - Část monografie knihy
Voláková, Martina - Sulajman, S. A. - Ahraf, A. M. - Kubička, D. - Čejka, Jiří
16. Zeolites and catalysts in petrochemistry, biomass uograding and fine chemical synthesis.
Silica and Silicates in Modern Catalysis. Trivandrum, Kerala: Transworld Research Network, 2010 - (Halasz, I.), s. 407-433. ISBN 978-81-7895-455-4
Grant CEP: GA MPO 2A-3TP1/063
Výzkumný záměr: CEZ:AV0Z40400503
Klíčová slova: zeolites * catalysis * catalytic zeolites
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie

Zeolites represent the most important group of inorganic materials applied in numerous large-scale chemical technologies around the world with increasing application in petrochemical production and fine chemical synthesis. In this chapter, we tried to highlight the most interesting achievements in reactions catalyzed by acid forms of different structural types of zeolites with particular attention paid to their structural features. Channel size, dimensionality of pore systems and their inner architecture are the most important textural features of zeolites controlling the site accessibility and the transport rates of reactants and products. Where efficient we tried also to relate the catalytic behavior of zeolites to particle morphology, dealumination, precoking or ionexchange whenever these modification were carried out aiming at the increase in the activity or selectivity of zeolites.
Trvalý link: http://hdl.handle.net/11104/0208622