Počet záznamů: 1
Cooperative interaction of protonated 1,4-diazabicyclo[2.2.2]octane with a hexaarylbenzene-based receptor: an experimental and theoretical study
- 1.0375925 - ÚMCH 2013 RIV AT eng J - Článek v odborném periodiku
Makrlík, E. - Toman, Petr - Vaňura, P. - Rathore, R.
Cooperative interaction of protonated 1,4-diazabicyclo[2.2.2]octane with a hexaarylbenzene-based receptor: an experimental and theoretical study.
Monatshefte fur Chemie. Roč. 143, č. 4 (2012), s. 563-568. ISSN 0026-9247. E-ISSN 1434-4475
Grant CEP: GA ČR(CZ) GAP205/10/2280
Výzkumný záměr: CEZ:AV0Z40500505
Klíčová slova: receptors * macrocycles * complexation
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 1.629, rok: 2012
The stability constant of a hexaarylbenzenebased receptor–protonated 1,4-diazabicyclo[2.2.2]octane complex dissolved in nitrobenzene saturated with water was determined from extraction experiments in the twophase water/nitrobenzene system and γ-activity measurements. Using quantum-mechanical calculations (DFT), the most probable structure of this complex was derived.
Trvalý link: http://hdl.handle.net/11104/0006933
Počet záznamů: 1