Laser Spark Formamide Decomposition Studied by FT-IR Spectroscopy

0370610 - ÚFCH JH 2012 RIV US eng J - Článek v odborném periodiku
Ferus, Martin - Kubelík, Petr - Civiš, Svatopluk
Laser Spark Formamide Decomposition Studied by FT-IR Spectroscopy.
Journal of Physical Chemistry A. Roč. 115, č. 44 (2011), s. 12132-12141. ISSN 1089-5639. E-ISSN 1520-5215
Grant CEP: GA AV ČR IAA400400705; GA AV ČR IAAX00100903; GA ČR GAP208/10/2302
Výzkumný záměr: CEZ:AV0Z40400503
Klíčová slova: FT-IR spectroscopy * high-power laser * induced dielectric-breakdown
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 2.946, rok: 2011

High-resolution FT-IR spectroscopy was used for the analysis of the products of formamide dissociation using a high-energy Asterix laser. In the experiment, the detected products of the formamide LIDB dissociation were hydrogen cyanide, ammonia, carbon monoxide, carbon dioxide, nitrous oxide, hydroxylamine, and methanol. The molecular dynamics of the process was simulated with the use of a chemical model. The chemistry shared by formamide and the products of its dissociation is discussed with the respect to the formation of biomolecules.
Trvalý link: http://hdl.handle.net/11104/0006792