On the role of radiative decay in the post-excitation dynamics of ionic rare-gas clusters

0370549 - ÚGN 2012 PL eng C - Konferenční příspěvek (zahraniční konf.)
Kalus, R. - Janeček, Ivan - Janča, T. - Naar, P. - Gadéa, F. X.
On the role of radiative decay in the post-excitation dynamics of ionic rare-gas clusters.
Central European Symposium on Theoretical Chemistry /10./. Torun: Nicolaus Copernicus University Faculty of Chemistry, 2011, s. 1-10.
[Central European Symposium on Theoretical Chemistry /10./. Torun (PL), 25.09.2011-28.09.2011]
Výzkumný záměr: CEZ:AV0Z30860518
Klíčová slova: radiative electronic transitions * decoherence effects * hemiquantal dynamics
Kód oboru RIV: DD - Geochemie

New multiscale scheme for including radiative electronic transitions into original hemiquantal dynamics considering decoherence effects and using the interaction model based on the diatomic in molecules approach with spin-orbit coupling was prepared. The new model was tested on rare gas tetramers fragmentation after sudden ionization. Results of simulations by the multiscale scheme show that theory prediction moves significantly closer to the experimental data if the radiative decay is included in theoretical modeling.
Trvalý link: http://hdl.handle.net/11104/0204327