Počet záznamů: 1
Copper-catalyzed activation of disulfides as a key step in the synthesis of benzothiazole moieties
- 1.0348739 - ÚOCHB 2011 RIV DE eng J - Článek v odborném periodiku
Hývl, Jakub - Šrogl, Jiří
Copper-catalyzed activation of disulfides as a key step in the synthesis of benzothiazole moieties.
European Journal of Organic Chemistry. -, č. 15 (2010), s. 2849-2851. ISSN 1434-193X. E-ISSN 1099-0690
Grant CEP: GA ČR GA203/08/1318
Výzkumný záměr: CEZ:AV0Z40550506
Klíčová slova: oxidation * copper * benzothiazole synthesis
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 3.206, rok: 2010
A convenient synthesis of substituted benzothiazoles has been accomplished by way of a copper catalyzed reaction of aromatic disulfide amines and aldehydes. The process, which involves copper catalyzed activation of disulfide functionality, proceeds in a tandem fashion via C–H bond activation, followed by aerobic oxidation of a resulting dihydrobenzothiazole intermediate. The scope and limitations of the reaction are demonstrated on a variety of substrates.
Trvalý link: http://hdl.handle.net/11104/0189178
Počet záznamů: 1