Počet záznamů: 1
Edge Effects in Voltage-step Transient I. Ohmic Losses in 1D Approximation (revisited)
- 1.0347058 - ÚCHP 2011 RIV CZ eng V - Výzkumná zpráva
Wein, Ondřej
Edge Effects in Voltage-step Transient I. Ohmic Losses in 1D Approximation (revisited).
Praha: Ústav chemických procesů AV ČR, v. v. i, 2010. 21 s. 3.
Grant CEP: GA ČR GA104/08/0428
Výzkumný záměr: CEZ:AV0Z40720504
Klíčová slova: voltage-step transient * ohmic loss * cottrell asymptote
Kód oboru RIV: CI - Průmyslová chemie a chemické inženýrství
Ohmic potential drop between the working and reference electrodes plays an important role in the early stage of the voltage-step transient process. Non-linear effect of the ohmic drop on the transient currents has been calculated for large voltage steps, assuming reversible behavior (negligible surface overpotential) of a redox couple O + ne = R. This report extends an older study by Wein (1991). In particular, it adds a series of analytic approximations and gives more accurate numerical solving.
Trvalý link: http://hdl.handle.net/11104/0187922
Počet záznamů: 1