Modular pyridine-type .I.P,N./I.-ligands derived from monoterpenes: application in asymmetric Heck addition

0194230 - UOCHB-X 20010337 RIV GB eng J - Článek v odborném periodiku
Malkov, A. V. - Bella, M. - Stará, Irena G. - Kočovský, P.
Modular pyridine-type .I.P,N./I.-ligands derived from monoterpenes: application in asymmetric Heck addition.
Tetrahedron Letters. Roč. 42, č. 16 (2001), s. 3045-3048. ISSN 0040-4039. E-ISSN 1873-3581
Výzkumný záměr: CEZ:AV0Z4055905
Klíčová slova: transition metal catalysis
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 2.280, rok: 2001

Novel (diphenylphosphinophenyl)pyridine ligands (+)-8, (+)-15, (-)-21, and (-)-26 were synthesized from (-)-á-pinene, (+)-3-carene, (+)-2-carene, and (-)-ŕ-pinene, respectively. Ligands (+)-15 and (-)-21 are quasi-enantiomeric, ligands 8 and 26 can be prepared in both enantiomeric forms from (+)- and (-)-enantiomers of ŕ- and á-pinene, respectively.
Trvalý link: http://hdl.handle.net/11104/0089916