Synthesis of poly[methyl(phenyl)silanediyl] containing 1,3,4-oxadiazole electron-transporting moieties

0189172 - UMCH-V 20033127 RIV DE eng J - Článek v odborném periodiku
Kotva, Rudolf - Cimrová, Věra - Výprachtický, Drahomír
Synthesis of poly[methyl(phenyl)silanediyl] containing 1,3,4-oxadiazole electron-transporting moieties.
Polymer Bulletin. Roč. 50, č. 4 (2003), s. 227-234. ISSN 0170-0839. E-ISSN 1436-2449
Grant CEP: GA ČR GA102/98/0696; GA ČR GA203/01/0512
Výzkumný záměr: CEZ:AV0Z4050913
Klíčová slova: oxadiazole derivative * poly[methyl(phenyl)silanediyl] * modified polysilanes
Kód oboru RIV: CD - Makromolekulární chemie
Impakt faktor: 0.795, rok: 2003

The new oxadiazole derivative containing amino group, 2-(4-aminophenyl)-5-(biphenyl-4-y1)- 1,3,4-oxadiazole (Oxad-NH2), was synthesized and attached to formylated poly[methyl(phenyl)silanediyl] (PMPSi) by acid-catalyzed condensation of the aldehyde with the amino group yielding a Schiff base. GPC analyses before and after modification reaction revealed that the attachment of Oxad-NH2 proceeded without degradation of the silicon backbone.
Trvalý link: http://hdl.handle.net/11104/0002627