0162179 - UIACH-O 200011 RIV NL eng J - Článek v odborném periodiku
Vespalec, Radim - Boček, Petr
Calculation of stability constants for the chiral selector-enantiomer interactions from electrophoretic mobilities.
Journal of Chromatography A. Roč. 875, 1+2 (2000), s. 431-445. ISSN 0021-9673. E-ISSN 1873-3778
Grant CEP: GA AV ČR IAA4031703; GA ČR GA203/99/0044; GA MŠMT VS96021
Kód oboru RIV: CB - Analytická chemie, separace
Impakt faktor: 2.551, rok: 2000

Obtaining of the raw mobility data, necessary for the calculation, is the critical step on the way to stability constants. The meaning and applicability of the particular constant depend on the constant type. The common method for the constant determination becomes unreliable for stronger complexing characterized by constants of the order of 10000 l/mol, for strong complexing giving the constants by one order of magnitude higher, the method is not applicable.
Trvalý link: http://hdl.handle.net/11104/0059499