Počet záznamů: 1
Highly siderophile element geochemistry and Re–Os isotopic systematics of carbonatites: Insights from Tamil Nadu, India
- 1.
SYSNO ASEP 0505893 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Highly siderophile element geochemistry and Re–Os isotopic systematics of carbonatites: Insights from Tamil Nadu, India Tvůrce(i) Ackerman, Lukáš (GLU-S) RID, SAI, ORCID
Polák, Ladislav (GLU-S) ORCID
Magna, T. (CZ)
Rapprich, V. (CZ)
Ďurišová, Jana (GLU-S) RID, SAI
Upadhyay, D. (IN)Zdroj.dok. Earth and Planetary Science Letters. - : Elsevier - ISSN 0012-821X
Roč. 520, 15 August 2019 (2019), s. 175-187Poč.str. 13 s. Forma vydání Tištěná - P Jazyk dok. eng - angličtina Země vyd. NL - Nizozemsko Klíč. slova carbonatite ; enriched mantle ; HSE ; metasomatism ; Re–Os isotopic systematics ; silicate Vědní obor RIV DB - Geologie a mineralogie Obor OECD Geology Způsob publikování Omezený přístup Institucionální podpora GLU-S - RVO:67985831 UT WOS 000474502200018 EID SCOPUS 85067071175 DOI https://doi.org/10.1016/j.epsl.2019.05.035 Anotace Carbonatite metasomatism has been widely implicated for worldwide mafic mantle suites but so far, no combined data have been available for highly siderophile element systematics (HSE – Os, Ir, Ru, Pt, Pd, Re) and Re–Os isotopic compositions in carbonatites themselves. We present the first systematic survey of the HSE and Re–Os isotopic compositions in a suite of well-characterized Neoproterozoic carbonatites, silicocarbonatites and associated silicate rocks (pyroxenites, monzogabbros, syenites) from south India in order to place constraints on the HSE systematics in carbonatite magmas, anchoring possible mantle sources of carbonatites and relationship to the ambient crustal lithologies as well as preliminary constraints on carbonatite metasomatism in Earth's mantle. The most plausible explanation for generally low HSE contents in calciocarbonatites from Tamil Nadu (∑HSE < 1.22 ppb) involves a low-degree (<1%) partial melting of the mantle source producing sulfur-saturated carbonatitic magmas leaving behind sulfide phases retaining HSE. The new data also indicate a strong FeO control on the distribution of Os and Pt during segregation of carbonatite melt from its enriched mantle source and/or melt differentiation. The combined 187Re/188Os values (from 0.10 to 217), 187Os/188Os ratios (0.186–10.4) and initial γOs values back-calculated to 800 Ma (from +0.1 to +6052) predict that most Tamil Nadu calciocarbonatites were plausibly derived from a carbonated peridotite source with <10% recycled component. This model would thus provide significant constraints on the origin/source of carbonatites, irrespective of their post-emplacement history. The unusual, volumetrically rare, Mg–Cr-rich silicocarbonatites (∑HSE = 14–41 ppb) display almost identical HSE patterns with those of host pyroxenites and predominantly high Pt (up to 38 ppb), the origin of which remains unknown. Positive co-variations between Pt, Pd and Re, and the well-developed positive correlation between Pt and MgO in these Mg–Cr-rich silicocarbonatites argue for a source coming predominantly from the upper mantle. The Re–Os isotopic systematics agree with direct incorporation of enriched mantle-derived material into parental melts but variable incorporation of potassium-rich crustal materials is evidenced by highly positive γOs800 Ma values for a sub-suite of Mg–Cr-rich silicocarbonatites, indicating intense fenitization. The highly radiogenic Os isotopic compositions of monzogabbros and a syenite argue for their derivation from crustal lithologies with no or only negligible contribution of mantle material. Collectively, low Ir, Ru, Pt and Pd contents found in the Tamil Nadu carbonatites appear to indicate the incapability to significantly modify the total budget of these elements in the Earth's mantle during carbonatite metasomatism. In contrast, very high Re/Os ratios found in some of the analyzed carbonatites, paralleled by extremely radiogenic 187Os/188Os signature, can produce large modification of the Re–Os isotopic composition of mantle peridotites during carbonatite melt percolation when high melt/rock ratios are achieved. Pracoviště Geologický ústav Kontakt Jana Popelková, popelkova@gli.cas.cz, Sabina Janíčková, Tel.: 233 087 272 Rok sběru 2020 Elektronická adresa https://www.sciencedirect.com/science/article/pii/S0012821X19303115?via%3Dihub
Počet záznamů: 1