Počet záznamů: 1
Adsorption Site-Dependent Mobility Behavior in Graphene Exposed to Gas Oxygen
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SYSNO ASEP 0498916 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Adsorption Site-Dependent Mobility Behavior in Graphene Exposed to Gas Oxygen Tvůrce(i) Blechta, Václav (UFCH-W) RID, ORCID
Drogowska, Karolina (UFCH-W) RID
Valeš, Václav (UFCH-W) RID, ORCID
Kalbáč, Martin (UFCH-W) RID, ORCIDZdroj.dok. Journal of Physical Chemistry C. - : American Chemical Society - ISSN 1932-7447
Roč. 122, č. 37 (2018), s. 21493-21499Poč.str. 7 s. Jazyk dok. eng - angličtina Země vyd. US - Spojené státy americké Klíč. slova field-effect transistors ; chemical-vapor-deposition ; walled carbon nanotube ; doped graphene ; layer graphene ; grown graphene Vědní obor RIV CF - Fyzikální chemie a teoretická chemie Obor OECD Physical chemistry CEP GA18-20357S GA ČR - Grantová agentura ČR LTC18039 GA MŠMT - Ministerstvo školství, mládeže a tělovýchovy Institucionální podpora UFCH-W - RVO:61388955 UT WOS 000445711100042 EID SCOPUS 85053787931 DOI 10.1021/acs.jpcc.8b06906 Anotace Transport characteristics of graphene field-effect transistors were measured in situ in oxygen/nitrogen atmospheres and at various temperatures. Mobilities of holes were extracted from transport characteristics as well as the doping level depending on the time of graphene exposure to oxygen/nitrogen atmosphere. The hole mobility showed significant decrease upon the oxygen adsorption to low energy adsorption sites (sp(2) carbon). However, it remained unaffected by the oxygen adsorption to high-energy adsorption sites which are represented by defects, impurities, transfer residuals, edges, and functional groups on graphene. The Dirac point was upshifted for both the low- and high-energy adsorption events. Activation energy of oxygen adsorption/desorption was estimated from temperature-dependent desorption rate coefficients as 215 and 450 meV for the low- and high-energy adsorption sites, respectively. Pracoviště Ústav fyzikální chemie J.Heyrovského Kontakt Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Rok sběru 2019
Počet záznamů: 1