Počet záznamů: 1

Superior Activity of Isomorphously Substituted MOFs with MIL-100(M=Al, Cr, Fe, In, Sc, V) Structure in the Prins Reaction: Impact of Metal Type

SYSNO ASEP	0473610
Druh ASEP	J - Článek v odborném periodiku
Zařazení RIV	J - Článek v odborném periodiku
Poddruh J	Článek ve WOS
Název	Superior Activity of Isomorphously Substituted MOFs with MIL-100(M=Al, Cr, Fe, In, Sc, V) Structure in the Prins Reaction: Impact of Metal Type
Tvůrce(i)	Gómez-Pozuelo, G. (ES) Cabello, C. P. (ES) Opanasenko, Maksym (UFCH-W)_{RID, ORCID} Horáček, Michal (UFCH-W)_{RID, ORCID} Čejka, Jiří (UFCH-W)_{RID, ORCID, SAI}
Zdroj.dok.	ChemPlusChem. - : Wiley - ISSN 2192-6506 Roč. 82, č. 1 (2017), s. 152-159
Poč.str.	8 s.
Jazyk dok.	eng - angličtina
Země vyd.	DE - Německo
Klíč. slova	impregnated mcm-41 catalyst ; organic frameworks mil-100 ; solid acid catalyst
Vědní obor RIV	CF - Fyzikální chemie a teoretická chemie
Obor OECD	Physical chemistry
CEP	GA14-07101S GA ČR - Grantová agentura ČR
Institucionální podpora	UFCH-W - RVO:61388955
UT WOS	000394182400014
EID SCOPUS	84995378019
DOI	10.1002/cplu.201600456
Anotace	The catalytic behavior of isomorphously substituted MIL-100(M) (M=Al, Cr, Fe, In, Sc, V) is investigated for the synthesis of nopol through the Prins condensation ofpinene with paraformaldehyde. The large mesoporous cages of the metal-organic frameworks provide a sustainable confinement for the formation of the target product (100% selectivity for nopol over all materials studied). MIL-100(Sc) and MIL-100(V) exhibit the highest yields (up to 90%) of nopol after just 20min from the beginning of the reaction, owing to their high concentrations of accessible Lewis sites possessing intermediate acidity. The high catalytic activity (reaching almost 90%pinene conversion) even upon decreasing the amount of catalyst from 100 to 25mg (0.025 and 0.0063g(catalyst)mmol(substrate)(-1), respectively), the stability of its structure, and the possibility to use it several times, make MIL-100(V) a promising material for applications in acid-catalyzed reactions under mild reaction conditions.
Pracoviště	Ústav fyzikální chemie J.Heyrovského
Kontakt	Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
Rok sběru	2018

Počet záznamů: 1