Počet záznamů: 1
3D microstructure of magnesium potassium phosphate ceramics from X-ray tomography: new insights into the reaction mechanisms
- 1.0496962 - UTAM-F 2020 RIV US eng J - Článek v odborném periodiku
Viani, Alberto - Sotiriadis, Konstantinos - Lanzafame, G. - Mancini, L.
3D microstructure of magnesium potassium phosphate ceramics from X-ray tomography: new insights into the reaction mechanisms.
Journal of Materials Science. Roč. 54, č. 5 (2019), s. 3748-3760. ISSN 0022-2461
Grant CEP: GA MŠk(CZ) LO1219
Klíčová slova: magnesium potassium phosphate ceramics * 3D microstructure * synchrotron X-ray computed microtomography
Kód oboru RIV: JN - Stavebnictví
Obor OECD: Materials engineering
Impakt faktor: 3.442, rok: 2018
Magnesium potassium phosphate ceramics are chemically bonded ceramics employed as biomaterials, in nuclear waste encapsulation and for concrete repair. The microstructure dictates material performance and depends on the raw mix composition. Synchrotron X-ray computed microtomography was employed to describe the 3D microstructure and its time evolution during hardening and gain insights into the reaction mechanisms. Any excess water with respect to the stoichiometry of the reaction brought about an increase in porosity, but, notably, a reduction in the average pore size. Crystals filled the water ‘pockets’ in the ceramic volume by growing larger, although less densely packed, increasing the complexity of the pore shape. Platelet over elongated crystal habit was favoured. Such a change in shape is likely related to a change in reaction mechanism, as crystallization from a gel-like amorphous precursor is hindered and progressively substituted by a through-solution mechanism. It is proposed that the time evolution of the microstructure is dictated by the balance between crystallization from amorphous precursor, prevailing in relatively ‘dense’ systems (with stoichiometric water or in low excess), and water segregation, prevailing at higher water contents. The former mechanism was shown to produce an increase in porosity with time, because of the density mismatch between the amorphous and the crystalline phase
Trvalý link: http://hdl.handle.net/11104/0289576