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Excess Adsorption Isotherms of Hydrogen on Activated Carbons from Agricultural Waste Materials.
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SYSNO ASEP 0474403 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Excess Adsorption Isotherms of Hydrogen on Activated Carbons from Agricultural Waste Materials. Author(s) Soukup, Karel (UCHP-M) RID, SAI, ORCID
Hejtmánek, Vladimír (UCHP-M) RID, SAI
Cruz, G.J.F. (PE)
Jandová, Věra (UCHP-M) RID, ORCID, SAI
Šolcová, Olga (UCHP-M) RID, ORCID, SAISource Title Chemical Engineering & Technology. - : Wiley - ISSN 0930-7516
Roč. 40, č. 5 (2017), s. 900-906Number of pages 7 s. Action International Conference on Process Integration, Modeling and Optimization for Energy Savings and Pollution Reduction (PRES) /19./ Event date 27.08.2016 - 31.08.2016 VEvent location Prague Country CZ - Czech Republic Event type WRD Language eng - English Country DE - Germany Keywords activated carbon ; hydrogen ; excess adsorption Subject RIV CI - Industrial Chemistry, Chemical Engineering OECD category Chemical process engineering R&D Projects GA15-14228S GA ČR - Czech Science Foundation (CSF) Institutional support UCHP-M - RVO:67985858 UT WOS 000399971100012 EID SCOPUS 85016313093 DOI 10.1002/ceat.201600610 Annotation Four activated carbons based on red mombin seeds, cocoa pod husk, the external part of mango pits and coffee husk were prepared by chemical activation using zinc chloride. Adsorption isotherms of hydrogen measured by volumetric method under supercritical conditions corresponding to the three temperature levels (77 K, 273 K and 298 K) and the pressure range of 0–1000 kPa were determined. The dependence of the hydrogen adsorbed amount on equilibrium pressure was linear for all adsorption isotherms measured at 273 and 298 K. Corresponding excess adsorption experimental data were fitted by Henry’s adsorption isotherm with excellent goodness of fit. Moreover, Dubinin-Radushkevich adsorption isotherm was demonstrated to fit the excess adsorption data at 77 K with high accuracy. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2018
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