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Termická oxidace oxidu uhelnatého ve spalných plynech
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SYSNO ASEP 0360264 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Termická oxidace oxidu uhelnatého ve spalných plynech Title Thermal Oxidation of Carbon Monoxide in Flue Gas Author(s) Hartman, Miloslav (UCHP-M) RID, ORCID, SAI
Trnka, Otakar (UCHP-M)
Veselý, Václav (UCHP-M) RID, SAI
Svoboda, Karel (UCHP-M) RID, ORCID, SAISource Title Chemické listy. - : Česká společnost chemická - ISSN 0009-2770
Roč. 105, č. 7 (2011), s. 546-552Number of pages 7 s. Language cze - Czech Country CZ - Czech Republic Keywords carbon monoxide ; rate of oxidation ; afterburner design Subject RIV CI - Industrial Chemistry, Chemical Engineering R&D Projects IAA400720701 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40720504 - UCHP-M (2005-2011) UT WOS 000293202500009 Annotation V práci je navržen a ověřen matematický model pro vysokoteplotní oxidaci toxického oxidu uhelnatého pro režim ideálně míchaného reaktoru. Numerická řešení modelových rovnic vymezují možnosti výkonu dopalovací komory za realistických pracovních podmínek. Description in English An ideally mixed flow model is developed for the high-temperature oxidation of toxic carbon monoxide into inert carbon dioxide occurring in an afterburner chamber. The extent of the oxidation reaction in oxygen – and water vapor – bearing flue gas is explored as a function of the relative throughput, the gas density, and the global rate of reaction. Steady-state experimental measurements of the CO, O2, CO2, and water vapor concentrations were conducted in a pilot-plant refractory afterburner fitted with a natural gas burner. The global burnout reaction is assumed to be first order in carbon monoxide and one-half order with respect to oxygen and water vapor. The numerical solutions of the model equations outline the possibilities and limitations for the performance of a well-mixed afterburner chamber (reactor) under realistic operating conditions. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2012
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