Number of the records: 1
Acid-base and Counter Ion Dependent Solid-state Assembly of a Ferrocene Beta-aminoalcohol and the Corresponding Ammonium Salt
- 1.
SYSNO ASEP 0101016 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Ostatní články Title Acid-base and Counter Ion Dependent Solid-state Assembly of a Ferrocene Beta-aminoalcohol and the Corresponding Ammonium Salt Title Ferrocen-Beta-aminoalkohol a jeho amoniová sůl: uspořádání molekul v pevné fázi závislé na povaze aniontů základního elektrolytu a na acidobazických podmínkách Author(s) Štěpnička, P. (CZ)
Císařová, I. (CZ)
Ludvík, Jiří (UFCH-W) RID, ORCIDSource Title Journal of Organometallic Chemistry. - : Elsevier - ISSN 0022-328X
Roč. 689, - (2004), s. 631-638Number of pages 8 s. Language eng - English Country CH - Switzerland Keywords ferrocene ; aminoalcohols ; hydrogen bonding Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects GP203/01/P002 GA ČR - Czech Science Foundation (CSF) GA203/99/M037 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z4040901 - UFCH-W Annotation 2-Ferrocenylmethyl)amino-2-methylpropan-1-ol (1) was synthesized and converted to the respective ammonium bromide ([1H]Br = 2) and dihydrogenphosphate ([1H]H2PO4 = 3). The solid-state structures of 1, 2 and the solvated salt 3 . 1/6 Et2O (3a) have been determined by X-ray diffraction. The solid-state assemblies of 1 and 2 are dominated by infinite ladder-like arrays interconnected by hydrogen bonds whereas the solid-state structure of 3a is built up from linear hydrogen-bonded dihydrogenphosphate chains, which are interlinked via hydrogen bonds to the cation [1H]+ into a complicated three-dimensional network. Compound 1 and its interactions with Bu4NBr and Bu4NH2PO4 in solution were further studied by electrochemical methods and NMR titrations. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2005
Number of the records: 1