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Overcoming P-glycoprotein-mediated multidrug resistance in cancer cells through micelle-forming PHPMA-b-PPO diblock copolymers for doxorubicin delivery

  1. 1.
    SYSNO ASEP0618471
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleOvercoming P-glycoprotein-mediated multidrug resistance in cancer cells through micelle-forming PHPMA-b-PPO diblock copolymers for doxorubicin delivery
    Author(s) Kaňa, Martin (MBU-M) ORCID
    Braunová, Alena (UMCH-V) RID
    Starenko, Daniil (MBU-M)
    Frejková, Markéta (UMCH-V) RID, ORCID
    Bouček, Jan (MBU-M)
    Říhová, Blanka (MBU-M) RID
    Kovář, Marek (MBU-M) RID, ORCID
    Etrych, Tomáš (UMCH-V) RID, ORCID
    Šírová, Milada (MBU-M) RID, ORCID
    Article number113645
    Source TitleJournal of Controlled Release. - : Elsevier - ISSN 0168-3659
    Roč. 381, May 10 (2025)
    Number of pages17 s.
    Languageeng - English
    CountryNL - Netherlands
    KeywordsMultidrug resistance ; P-glycoprotein inhibition ; Sensitization to chemotherapy ; Intracellular ATP depletion ; HPMA copolymer ; PPO ; Diblock copolymers ; Drug delivery system
    OECD categoryImmunology
    R&D ProjectsNU21-03-00273 GA MZd - Ministry of Health (MZ)
    LX22NPO5102 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
    Method of publishingOpen access
    Institutional supportMBU-M - RVO:61388971 ; UMCH-V - RVO:61389013
    UT WOS001457041100001
    EID SCOPUS105000612958
    DOI https://doi.org/10.1016/j.jconrel.2025.113645
    AnnotationMultidrug resistance (MDR) represents one of the major concerns in cancer therapy as it may cause reduced efficacy of chemotherapeutic drugs. The study explores the potential of novel amphiphilic diblock (DB) micelle forming copolymers composed of poly[N-(2-hydroxypropyl)methacrylamide]-based copolymers and poly(propylene oxide) to overcome MDR mechanisms. The DB copolymers and their doxorubicin (Dox) conjugates significantly inhibited drug efflux in chemoresistant cancer cells by depletion of intracellular ATP, resulting in increased Dox accumulation. Mechanisms involved in MDR inhibition are shown. Copolymers with additionally loaded PPO in the micelle core demonstrated superior efficacy in vitro and in vivo in treatment of experimental murine tumor CT26. The ATP depletion capacity was also demonstrátor in patient-derived xenograft (PDX) model.
    WorkplaceInstitute of Microbiology
    ContactEliška Spurná, eliska.spurna@biomed.cas.cz, Tel.: 241 062 231
    Year of Publishing2026
    Electronic addresshttps://www.sciencedirect.com/science/article/pii/S0168365925002652
Number of the records: 1  

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