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AMINE-FUNCTIONALIZED POROUS POLYMERS FOR SELECTIVE CO2 ADSORPTION. číslo posteru P27, p. 82
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SYSNO ASEP 0542797 Document Type A - Abstract R&D Document Type The record was not marked in the RIV R&D Document Type Není vybrán druh dokumentu Title AMINE-FUNCTIONALIZED POROUS POLYMERS FOR SELECTIVE CO2 ADSORPTION. číslo posteru P27, p. 82 Author(s) Setničková, Kateřina (UCHP-M) RID, ORCID, SAI
Jeřábek, Karel (UCHP-M) RID, ORCID, SAI
Strašák, Tomáš (UCHP-M) RID, ORCID, SAI
Soukup, Karel (UCHP-M) RID, SAI, ORCIDSource Title Book of Abstracts. - Prague, 2021 Number of pages 1 s. Action mezinárodní chemicko-technologická virtuální konference /8./ Event date 03.05.2021 - 05.05.2021 VEvent location Prague Country CZ - Czech Republic Event type EUR Language eng - English Keywords CO2 adsorption ; porous polymer ; dendrimer Subject RIV CC - Organic Chemistry OECD category Organic chemistry R&D Projects GC19-23760J GA ČR - Czech Science Foundation (CSF) Institutional support UCHP-M - RVO:67985858 Annotation Porous materials have always attracted high scientific interest because of their outstanding performance and potential applications in various fields, including adsorption and gas separation. Hyper-crosslinked polymers (HCPs) have several advantages over other porous materials, they show extremely high surface areas and porosity, low density, outstanding adsorption properties, high chemical, and thermal stability.
Herein, we reported a synthesis, characterization, and the CO2 (and other gases) adsorption performance of series of novel styrene-divinylbenzene based HCPs. The material was prepared in two steps. The first step involved the radical copolymerization of divinylbenzene (DVB) and 4-vinylbenzyl chloride (VBC), under solvothermal condition to generate porous polymers with high surface area above 700 m2 g−1. In the second step, various polyamine species were applied to react with the alkyl chloride groups and functionalize the pore surface to improve the CO2/N2 and CO2/CH4 selectivity.Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2022
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