An electrochemical viewpoint on the solubility of silver halides in water

0533530 - ÚFCH JH 2021 RIV DE eng J - Journal Article
Kakiuchi, T. - Samec, Zdeněk
An electrochemical viewpoint on the solubility of silver halides in water.
Journal of Solid State Electrochemistry. Roč. 24, č. 11-12 (2020), s. 3185-3189. ISSN 1432-8488. E-ISSN 1433-0768
Institutional support: RVO:61388955
Keywords : temperature molten-salt * electrical double-layer * nonpolarized interface * mutual solubilities * ionic liquids * zero charge * adsorption * electrocapillarity * halogen * phase * Silver halides * Solubility product * Nernst * Standard ion transfer potential * Solubility * Distribution potential * Ion transfer
OECD category: Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Impact factor: 2.647, year: 2020
Method of publishing: Limited access

An electrochemical view on the solubility product of sparingly soluble salts in water, which Nernst introduced in 1892, is helpful for better understanding of the precipitation equilibria. Specifically exemplified is the solubility of silver halides in terms of the partitioning of the salt-constituting ions between the ionic crystal and the adjacent solution.
Permanent Link: http://hdl.handle.net/11104/0311903