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Swollen Polyhedral Volume of the anti-B18H22 Cluster via Extensive Methylation: Anti-B18H8Cl2Me12

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    0522774 - ÚACH 2021 RIV US eng J - Journal Article
    Londesborough, Michael Geoffrey Stephen - Lang, Kamil - Clegg, W. - Waddell, P. G. - Bould, Jonathan
    Swollen Polyhedral Volume of the anti-B18H22 Cluster via Extensive Methylation: Anti-B18H8Cl2Me12.
    Inorganic Chemistry. Roč. 59, č. 5 (2020), s. 2651-2654. ISSN 0020-1669. E-ISSN 1520-510X
    R&D Projects: GA ČR(CZ) GA18-20286S
    Grant - others:AV ČR(CZ) StrategieAV21/10
    Program: StrategieAV
    Institutional support: RVO:61388980
    Keywords : Boron * Absorption * Cluster chemistry * Fluorescence
    OECD category: Inorganic and nuclear chemistry
    Impact factor: 5.165, year: 2020
    Method of publishing: Limited access
    https://doi.org/10.1021/acs.inorgchem.0c00179

    Methylation of anti-B18H22 (1) affords the first example of alkyl substitution of terminal hydrogen atoms on the fluorescent octadecaborane-22 molecule to give highly methylated 2,2′-Cl2-1,1′,3,3′,4,4′,7,7′,8,8′,10,10′-Me12-anti-B18H8 (2). This extensive chemical substitution leads to a swelling in the polyhedral volume of the 18-vertex boron atomic skeleton of the molecule and an enhancement of the absorption and solubility characteristics of this highly fluorescent molecule. We propose this “swollen polyhedral volume“ to be the result of a marked increase in the relative positivity of the “cluster-only total charge“ of the boron atomic skeleton caused by the combined electron-withdrawing capacity of the 12 methyl groups. Enhancement in the absorption and solubility properties may be crucial in the design of new borane-based laser materials.
    Permanent Link: http://hdl.handle.net/11104/0307214


    Research data: CCDC, CCDC, ACS publications
     
     
Number of the records: 1  

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