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The effect of a thiophene ring in the outer position on mesomorphic properties of the bent-shaped liquid crystals

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    0348205 - FZÚ 2011 RIV GB eng J - Journal Article
    Kozmik, V. - Polášek, P. - Seidler, A. - Kohout, M. - Svoboda, J. - Novotná, Vladimíra - Glogarová, Milada - Pociecha, D.
    The effect of a thiophene ring in the outer position on mesomorphic properties of the bent-shaped liquid crystals.
    Journal of Materials Chemistry. Roč. 20, č. 35 (2010), s. 7430-7435. ISSN 0959-9428
    R&D Projects: GA AV ČR IAA100100911; GA AV ČR(CZ) GA202/09/0047
    Institutional research plan: CEZ:AV0Z10100520
    Keywords : bent-shaped molecules * thiophene * x-ray diffraction
    Subject RIV: BM - Solid Matter Physics ; Magnetism
    Impact factor: 5.101, year: 2010

    Novel symmetrical and non-symmetrical bent-shaped compounds with the naphthalene central core possessing an outer thiophene unit in the lengthening arm were synthesised. Their mesomorphic behaviour was studied using optical polarising microscopy, DSC, and electrooptic methods. Structures of mesophases were identified by X-ray diffraction and parameters established. In the case of one thiophene unit in molecular arm we succeeded in preparation of mesogenic bent-shaped material with various lateral substitutions on the central naphthalene core and character of the terminal chain.
    Permanent Link: http://hdl.handle.net/11104/0006041

     
     
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