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Resonance energy in benzene and ethene derivatives in the gas phase as a measure of resonance ability of various functional groups

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    0193699 - UOCHB-X 20000049 RIV GB eng J - Journal Article
    Exner, Otto - Böhm, S.
    Resonance energy in benzene and ethene derivatives in the gas phase as a measure of resonance ability of various functional groups.
    Journal of the Chemical Society-Perkin Transactions 2. č. 9 (2000), s. 1994-1999. ISSN 1472-779X
    R&D Projects: GA ČR GA203/99/1454; GA AV ČR KSK2055603; GA AV ČR KSK2004601
    Institutional research plan: CEZ:AV0Z4055905
    Subject RIV: CC - Organic Chemistry
    Impact factor: 1.770, year: 2000

    Three sets of isodesmic reactions in the gas phase were constructed in which a variable functional group is transferred from a saturated to an unsaturated residue. Reaction enthalpies were considered as new possible scales of resonance effect. All scales are only partly parallel to the common scales of substituent constants.
    Permanent Link: http://hdl.handle.net/11104/0089394

     
     

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