Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15]

0050989 - ÚACH 2007 RIV GB eng J - Journal Article
Carr, MJ. - Londesborough, Michael Geoffrey Stephen - McLeod, A.R.H. - Kennedy, JD.
Macropolyhedral boron-containing cluster chemistry. Metallathiaboranes from S2B17H17: isolation and characterisation of [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B16H16] and [(eta(6)-(MeC6H4Pr)-Pr-iso)RuS2B15H15].
[Chemie makropolyhedrálních klastrů obsahujících bor.Metallathiaborany odvozené z S2B17H17: izolace a charakterizace.]
Dalton Transactions. -, č. 30 (2006), s. 3624-3626. ISSN 1477-9226. E-ISSN 1477-9234
Institutional research plan: CEZ:AV0Z40320502
Keywords : anion * metallaboranes * thiaborane
Subject RIV: CA - Inorganic Chemistry
Impact factor: 3.012, year: 2006

Deprotonation of [S2B17H17] 1 with NaH and subsequent reaction with [{RuCl2(eta(6)-MeC6H4 Pr-iso)}(2)] gives new nineteen-vertex [(eta(6)- MeC6H4 Pr-iso) RuS2B16H16] 2, with a nido {SB9} unit and an arachno-type {RuSB9} unit conjoined with a B - B edge in common, and new eighteen-vertex [(eta(6)-MeC6H4 Pr-iso) RuS2B15H15] 3 with a nido {RuSB9} subcluster fused via a common B - B edge to a nido {B-8} subcluster that is additionally linked exo to the {RuSB9} unit by a bridging sulfur atom that is held endo to the {B-8} unit.

Chemie makropolyhedrálních klastrů obsahujících bor. Metallathiaborany odvozené z S2B17H17: izolace a charakterizace.
Permanent Link: http://hdl.handle.net/11104/0140991