Počet záznamů: 1

Low-dimensional compounds containing cyanido groups. XXI. Crystal structure, spectroscopic, thermal and magnetic properties of two polymorphous modifications of [Cu(men)2Pt(CN)4]n complex (men = N-methyl-1,2-diaminoethane)

  1. 1.
    0363770 - FZU-D 2012 RIV NL eng J - Článek v odborném periodiku
    Vavra, M. - Potočňák, I. - Čižmár, E. - Kajňáková, M. - Dušek, Michal - Schmidt, H. - Ozerov, M. - Zvyagin, S.A. - Dlháň, L. - Boča, R.
    Low-dimensional compounds containing cyanido groups. XXI. Crystal structure, spectroscopic, thermal and magnetic properties of two polymorphous modifications of [Cu(men)2Pt(CN)4]n complex (men = N-methyl-1,2-diaminoethane).
    Polyhedron. Roč. 30, č. 2 (2011), 269-278 ISSN 0277-5387
    Grant ostatní: AVČR(CZ) Praemium Academiae
    Výzkumný záměr: CEZ:AV0Z10100521
    Klíčová slova: 1D crystal structure * polymorphism * N-methyl-1,2-diaminoethane * tetracyanidoplatinate(II) * antiferromagnetic exchange
    Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
    Impakt faktor: 2.057, rok: 2011

    Violet (1) and blue (2) polymorphous modifications of [Cu(men)2Pt(CN)4]n (men = N-methyl-1,2-diaminoethane)have been prepared and investigated by IR and UV–vis spectroscopy, thermal analysis, measurement of magnetic data and X-ray structural analysis. The temperature dependence of the magnetic susceptibility suggests the presence of a weak antiferromagnetic exchange coupling between Cu(II) atoms in compound 1.
    Trvalý link: http://hdl.handle.net/11104/0199440