Počet záznamů: 1

Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen

  1. 1.
    0361469 - UOCHB-X 2012 RIV GB eng J - Článek v odborném periodiku
    Beier, Petr - Pastýříková, Tereza
    Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen.
    Tetrahedron Letters. Roč. 52, č. 34 (2011), s. 4392-4394 ISSN 0040-4039
    Grant CEP: GA ČR GAP207/11/0344
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: pentafluorosulfanyl group * vicarious nucleophilic substitution * hydroxylation
    Kód oboru RIV: CC - Organická chemie
    Impakt faktor: 2.683, rok: 2011

    Para- and meta-nitro-(pentafluorosulfanyl)benzenes react with anions of cumyl hydroperoxide in the presence of t-BuOK in liquid ammonia to form nitro-(pentafluorosulfanyl)phenols. Their reduction with hydrogen in the presence of Raney-Nickel provides amino-(pentafluorosulfanyl)phenols.
    Trvalý link: http://hdl.handle.net/11104/0198776