Počet záznamů: 1

HCB(11)(CF(3))(n)F(11-n)(-): Inert Anions with High Anodic Oxidation Potentials

  1. 1.
    0361445 - UOCHB-X 2012 RIV US eng J - Článek v odborném periodiku
    Fete, M. G. - Havlas, Zdeněk - Michl, Josef
    HCB(11)(CF(3))(n)F(11-n)(-): Inert Anions with High Anodic Oxidation Potentials.
    Journal of the American Chemical Society. Roč. 133, č. 11 (2011), s. 4123-4131 ISSN 0002-7863
    Grant CEP: GA AV ČR IAA400550708
    Grant ostatní:NSF(US) CHE-0848477
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: icosahedral anions * fluorinated carbaborane anions * redox potentials * gas-phase elektron detachment energy
    Kód oboru RIV: CC - Organická chemie
    Impakt faktor: 9.907, rok: 2011

    A new type of low nucleofile anions of general formula HCB11(CF3)nF11-n were prepared. All prepared compound were electrochemically characterized and their electrochemical potentials were compared with calculations predicting gas-phase electron detachment energy of these anions.
    Trvalý link: http://hdl.handle.net/11104/0198755